Synthesis and Biological Activity of Copper (Ii), Nickel(Ii) and Cobalt(Ii) With Tetradentate Schiff Bases Complexes Derived From 2-Hydroxy-1- Naphthaldehyde and Aromatic Diamines
Keywords:
Schiff Bases, Biological Activity, 2-Hydroxy-1-naphthaldehyde, Aromatic DiaminesAbstract
2-hydroxy-1-napthaldehyde reacted with diaminophenol in absolute EtOH in a ratio 2:1 to give new Schiff bases (H2L1, H2L2 and H2L3). The obtained Schiff bases which were in tautomeric equilibrium (enol-imine O-H…N, keto-amine O…H-N forms) were used as ligands to coordinate Cu (II), Ni (II), and Co (II) leading complexes. The ligands and the complexes were characterized by physicochemical, elemental and spectroscopic analyses. The complexes exhibited 1:1 metal to ligand coordination ratio ( ML1) , (ML2), (ML3). Both Ligands and complexes were evaluated for antibacterial properties using disc diffusion method.. The complexes showed higher activity than the free ligands.
References
Aliyu H.N., Sani U., Galadma A.,“Synthesis, antibacterial and antifungal Investigation of Fe(II) complexes with Schiff Bases Derived from 2-hydroxy-1-naphthaldehyde and some aliphatic diamines”. European journal of scientific research, 2011, 59(2); 276-283.
Asad M., Sepehrpour H. and Mohammad K., Tetradentate Schiff base ligands of 3,4-diaminobenzophenone: Synthesis, characterization and thermodynamics of complex
formation with Ni(II), Cu(II) and Zn(II) metal ions, J. Serb. Chem. Soc. 2011, 76 (0); 1–12
Baseer M. A., Jadhav V.D., Phule R.M., Archana Y.V., Vibhute Y.B. ”Synthesis and antimicrobial activity of some new Schiff bases”, Orient J Chem ., 2000, 16; 553-556.
Cotton f.A. and Wilkinson G. , Advanced inorganic chemistry, interscience Pub.New York, 3rd Edition, 1972, p 624.
Desai S.B., Desai P.B., Desai K.R.”Synthesis of some Schiff bases, Thiozolidones, and azetidinones derived from 2,6-diaminobenzo(1,2-d:4,5-d9bisthiazol and their anticancer activities”, Heterocycl. Commun, 2001, 7; 83-90.
Dugas H. and Penny CH. Bioorganic Chemistry. (Springer advanced texts in chemistry. Herausgegeben von Ch. R. CANTOR), 508 Seiten, 79 Abb., 1 Schema, 7 Tab. Springer-Verlag, New York, Heidelberg, Berlin, 1981.
Eder T.G., Cavalheiro Francisco C.D. Lemos,JuÂlio Zukerman Schpector, Edward R. Dockal. “The thermal behaviour of nickel, copper and zinc complexes with the Schiff bases cis- and trans-N,N-bis(salicylidene)-1,2-cyclohexadiamine (Salcn)”, Thermochimica Acta 2001, 370 ;129±133.
Feng, X.; Wang, J. G.; Xie, C. Z.; Ma, N. “Synthesis, crystal structure and magnetic properties of 4,4'-bipyridine bridged dinuclear iron(III) complex containing N,N'-bis(Salicylideneamino)ethanato”. Anorg Allg Chem., 2007, 633; 2085
Fernandez-G, J.M.; del Rio-Portilla, f.; Qwiroz-Garcia, B.;Toscano, R.A.;Salcido,R. .” The structure of some ortho-hydroxy Schiff base ligands”. J Mol Struct., 2001, 561;197-207.
FCGI : “Synthesis, Biological, Spectral and Thermal Investigations of Co(II) and ]Ni(II) complexes, 2008”; www.pumedcentral.nih.gov/artclerender.fegi.
Henrici-Olive G. and Olive S. The Chemistry of the Catalyzed Hydrogenation of
Carbon Monoxide (Springer, Berlin,), 1984.
Karia F.D., Parsania P.H. ” Synthesis and biological activities of Schiff bases of bisphenol-C”, Asian Journal of Chemistry, 1999, 11; 991-995.
Margerum J. D. and Miller L. (). J Photochronism (Wiley, New York,), 1971.
More p.G., Bhalvankar R.B., pattar S.C.” Synthesis and biological activities of Schiff bases of aminothiazoles”,Journal Indian Chem Soc., 2001, 78; 474-475.
Nathan l.C., Koehne J.E., Gilmore J.M., Hannibal K.A., Dewhirst W.E., Mai T.D.” The X-ray structures of a series of copper (II) complexes with tetradentate Schiff base ligands derived from salicylaldehyde and polymethylenediamines of varying chain length”. Polyhedron , 2003, 22; 887-894,.
Ourani A., ourani K., Moumeni W. and Sibous L. “Unsymetrical tetradentate Schiff base complexes derived from 2,3-diaminophenol and salicylaldehyde or 5-bromosalicylaldehyde”, transition Metal chemistry, 2006, 31;169-175.
Panova G.V.; Potapov, V.M.; Turovets, I.M.; Glub, E.G. Zh obshch khim 53:1612, English translation, J. Gen, chem..,USSR,1983, 53;1452.
Ramon, N,;Mutijuai, V.; Rovichandran, S.; Kultandaisamy.A. ”Synthesis , characterization and electrochemical behavior of Cu(II), Co(II), Ni(II), and Zn(II) complexes derived from acetyl acetone and p- anisidine and their antimicrobial activity”, Proc. Ind. Aca. Sci., 2003, 115(5);161-167.
Samadhiya S., Halve A. ”Synthesis utility of Schiff bases as potential herbicidal agents”, .Orient J Chem., 2001, 17;119-122.
Sari N., Arslan S., Logoglu E. and Sakiyan L. “Antibacterial Activities of some new Amino acid Schiff Bases”, G,U.J.Sci., 2003, 16(2); 283-288.
Sheldon R.A. and Kochi l.K.” Metal Catalysed of Organic compounds”. Academic press. New York, 1981.
Sinddiqui H.L., Iqbal A., Ahmed S., Weaver G.W.(). ” Synthesis and spectroscopic studies of new Schiff Bases”, Molecules, 2006, 11; 206-211.
Spinu C. and Kirza A. “Co(II), Ni(II) and Complexes of Bidentate Schiff Bases, Acta. Chim. Slov”. 2000, 47; 179.
Ünver, H.; Zengin, D.M.; Güven, k. ”Intramolecular hydrogen bonding and tautomerismin 1-(N-(4-bromophenyl)) aminomethylidene-2(1H) naphthalonene”, J.Chem.Crystalloger, 2000, 30; 359-364.
Asad M., Sepehrpour H. and Mohammad K., Tetradentate Schiff base ligands of 3,4-diaminobenzophenone: Synthesis, characterization and thermodynamics of complex
formation with Ni(II), Cu(II) and Zn(II) metal ions, J. Serb. Chem. Soc. 2011, 76 (0); 1–12
Baseer M. A., Jadhav V.D., Phule R.M., Archana Y.V., Vibhute Y.B. ”Synthesis and antimicrobial activity of some new Schiff bases”, Orient J Chem ., 2000, 16; 553-556.
Cotton f.A. and Wilkinson G. , Advanced inorganic chemistry, interscience Pub.New York, 3rd Edition, 1972, p 624.
Desai S.B., Desai P.B., Desai K.R.”Synthesis of some Schiff bases, Thiozolidones, and azetidinones derived from 2,6-diaminobenzo(1,2-d:4,5-d9bisthiazol and their anticancer activities”, Heterocycl. Commun, 2001, 7; 83-90.
Dugas H. and Penny CH. Bioorganic Chemistry. (Springer advanced texts in chemistry. Herausgegeben von Ch. R. CANTOR), 508 Seiten, 79 Abb., 1 Schema, 7 Tab. Springer-Verlag, New York, Heidelberg, Berlin, 1981.
Eder T.G., Cavalheiro Francisco C.D. Lemos,JuÂlio Zukerman Schpector, Edward R. Dockal. “The thermal behaviour of nickel, copper and zinc complexes with the Schiff bases cis- and trans-N,N-bis(salicylidene)-1,2-cyclohexadiamine (Salcn)”, Thermochimica Acta 2001, 370 ;129±133.
Feng, X.; Wang, J. G.; Xie, C. Z.; Ma, N. “Synthesis, crystal structure and magnetic properties of 4,4'-bipyridine bridged dinuclear iron(III) complex containing N,N'-bis(Salicylideneamino)ethanato”. Anorg Allg Chem., 2007, 633; 2085
Fernandez-G, J.M.; del Rio-Portilla, f.; Qwiroz-Garcia, B.;Toscano, R.A.;Salcido,R. .” The structure of some ortho-hydroxy Schiff base ligands”. J Mol Struct., 2001, 561;197-207.
FCGI : “Synthesis, Biological, Spectral and Thermal Investigations of Co(II) and ]Ni(II) complexes, 2008”; www.pumedcentral.nih.gov/artclerender.fegi.
Henrici-Olive G. and Olive S. The Chemistry of the Catalyzed Hydrogenation of
Carbon Monoxide (Springer, Berlin,), 1984.
Karia F.D., Parsania P.H. ” Synthesis and biological activities of Schiff bases of bisphenol-C”, Asian Journal of Chemistry, 1999, 11; 991-995.
Margerum J. D. and Miller L. (). J Photochronism (Wiley, New York,), 1971.
More p.G., Bhalvankar R.B., pattar S.C.” Synthesis and biological activities of Schiff bases of aminothiazoles”,Journal Indian Chem Soc., 2001, 78; 474-475.
Nathan l.C., Koehne J.E., Gilmore J.M., Hannibal K.A., Dewhirst W.E., Mai T.D.” The X-ray structures of a series of copper (II) complexes with tetradentate Schiff base ligands derived from salicylaldehyde and polymethylenediamines of varying chain length”. Polyhedron , 2003, 22; 887-894,.
Ourani A., ourani K., Moumeni W. and Sibous L. “Unsymetrical tetradentate Schiff base complexes derived from 2,3-diaminophenol and salicylaldehyde or 5-bromosalicylaldehyde”, transition Metal chemistry, 2006, 31;169-175.
Panova G.V.; Potapov, V.M.; Turovets, I.M.; Glub, E.G. Zh obshch khim 53:1612, English translation, J. Gen, chem..,USSR,1983, 53;1452.
Ramon, N,;Mutijuai, V.; Rovichandran, S.; Kultandaisamy.A. ”Synthesis , characterization and electrochemical behavior of Cu(II), Co(II), Ni(II), and Zn(II) complexes derived from acetyl acetone and p- anisidine and their antimicrobial activity”, Proc. Ind. Aca. Sci., 2003, 115(5);161-167.
Samadhiya S., Halve A. ”Synthesis utility of Schiff bases as potential herbicidal agents”, .Orient J Chem., 2001, 17;119-122.
Sari N., Arslan S., Logoglu E. and Sakiyan L. “Antibacterial Activities of some new Amino acid Schiff Bases”, G,U.J.Sci., 2003, 16(2); 283-288.
Sheldon R.A. and Kochi l.K.” Metal Catalysed of Organic compounds”. Academic press. New York, 1981.
Sinddiqui H.L., Iqbal A., Ahmed S., Weaver G.W.(). ” Synthesis and spectroscopic studies of new Schiff Bases”, Molecules, 2006, 11; 206-211.
Spinu C. and Kirza A. “Co(II), Ni(II) and Complexes of Bidentate Schiff Bases, Acta. Chim. Slov”. 2000, 47; 179.
Ünver, H.; Zengin, D.M.; Güven, k. ”Intramolecular hydrogen bonding and tautomerismin 1-(N-(4-bromophenyl)) aminomethylidene-2(1H) naphthalonene”, J.Chem.Crystalloger, 2000, 30; 359-364.
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Published
2013-06-30
How to Cite
M., M. K., Basheer, H. A., & Ibrahiem., A. A. (2013). Synthesis and Biological Activity of Copper (Ii), Nickel(Ii) and Cobalt(Ii) With Tetradentate Schiff Bases Complexes Derived From 2-Hydroxy-1- Naphthaldehyde and Aromatic Diamines. Science Journal of University of Zakho, 1(1), 246–252. Retrieved from https://sjuoz.uoz.edu.krd/index.php/sjuoz/article/view/81
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