Synthesis and Characterization of Co+2,Ni+2,Cu+2 ,Zn+2 and Hg+2 Complexes With 1,1,2,2-Tetrakis (Sodium Thiolactate) Ethylene
Keywords:
sodium thiolactate, direct reaction, tetranuclear complexesAbstract
The new ligand 1,1,2,2-tetrakis(sodium thiolactate) ethylene, has been prepared from the reaction of disodium salt of thiolactic acid and tetrachloroethylene in (4:1) molar ratio. Di and tetranuclear complexes were obtained by direct reaction of the above ligand with Co+2,Ni+2,Cu+2 , Zn+2 and Hg+2 metal ion in (1:2) and (1:4) ligand to metal molar ratio.
The prepared complexes were characterized by elemental analysis, spectral studies (FTIR.,UV/vis), magnetic measurements, conductivity measurements. Electronic spectra and magnetic moment values indicate the presence of tetrahedral geometric around the metal ions.
References
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Almatarneh M., (2011), Reaction of Pd+2 and Pt+2 with
pyrrolidinedithio carbamate and cystine ligands, synthesis and DFT
calaculation, J. Sulfur Chem.,32(2),159-169.
AL-Allaf T.A.K. and Buttrus N. H., (1994), Coordination complexes of
Uranium (VI),Thorium(IV),Cerium (III) and Lanthanum (III) with
various multidentade ligands, ABATH AL-YAEMOK 3,101-110.
AL-Allaf T.A.K.; Buttrus N.H. and Hitchcock P.B.,(1997),Palladium and
Platinum (II) complexes with arylthioethene, Asia.J. Chem., 9(2),
187-194.
Aydin, M., Arsu N.,Yagci Y., Jackusch S. and Turro N.J. (2005),
Mechanistic study of photointiated free radical polymerization using
thioxathone thio acetic acid, Macromolecules, 38,4133-4138
Banger K.K., Duraj S.A., Fanwick P.E., Hehemann D.G., Hepp A. F. and
Matrok R.A., (2004), Synthsis and structural characterization of novel
indium mercapto derivative [ClIn(SCH2(COO)2]2-[4-MePyH)2]+2,
NASAITM,212289.
Bhatti M.,Ali S.,Huma F. and Shahazadi S., (2005), Organo tin (IV)
derivatives of N-maleonyl amino acids. Their synthesis and
structural elucidation, Turk J.Chem.,29,463-470.
Buttrus N.H. and Saeed F.T.,(2012),Bis (N-methyl benzimidazolium-2-
thio) ethane,propane or butane and its Co(II),Ni(II),Cu(II) and Zn(II)
ionic salts, International J.Chem.,22(2),117-122.
Buttrus N.H., Abd alrazaq E.A.and AL-Sger A.K., Synthesis and
characterization of some new semiconductinc dinuclear platinum (II)
complexes containing 1,1,2,2-tetrakis-(substituted phenylthio)
ethylene, (2007) Int.J.Chem.Sci., 5(3), 1111-1120,(2007).
Buttrus N.H.,AL-Smaan S.H.and AL-Asalli S.M.,(2010),Mono,di- and tri-nuclear complexesofCo(II), Ni(II), Cu(II) and Zn(II) with1,4 bis(sodium thioglycolate) butane, 20(1), 37-42.
Buttrus N.H., AL-Smaan S.H.and AL-Asalli S.M.,(2013),Gold(III)complexes with thiolactate and bis(1,4-sodium thiolactate) butane ligands, International J. Chem., accepted (2013).
Buttrus N.H., Mohamed S.M, Sabah A.A and Abdalrazaq E.A., Asian
(2013), Synthesis and characterization of Ni+2, Cu+2 and Zn+2
complexes with benzimidazole-2-thionate, diphosphene and their
reaction with iodine, J.Chem., 25(9), 14125, (2013).
Cotton F.A.; Wilkinson G.; Murillo C.A. andBochmann M., (1999)
"AdvanceInorganic Chemistry", 6th Ed., Joh. Wiley and Sons,New
York, 810-842
Geary W.J.(1971),The use conductivity measurements in organic
solvents for characterization of coordination compounds, Coord.
Chem.Rev.,7,8-81.
K.Nakamoto,(1997),"Infrared of inorganic and coordination compounds", 6th Edition, John Wiley New York.
Konno T., Yonenobu K.,Hidaka J. and Okamoto K., (1994), A New class
of s-bridged hexanuclear complexes with amino thiolate ligands.
Formation and structural characterization of[PdII2{NiII(aet)2}x{PdII(aet)2}4-x]Br4 (x = 0-4 ;aet = 2-aminoethanethiolate), Inorg.Chem.,33, 538.
Patel K.S. and Ikekwere P.O,1981,Magentic and spectral properties of
Cu(II) cyanobenzoates, J. Inorg. Nucl. Chem., 43,51-55
Sinfelt J. H., (1983), "Bimetallic Catalysis", Wiely, New York, (1983).
Stephan D.W., (1989), Early late heterobimetallies, Coord. Chem. Rev.,
95, 41.
Wenzel B.,Lonnecke P., Stender M. and Hey Hawkins E., (2002),
Eraly/ Late heterobimetallic, unusual tetranuclear Zr/Ni and
octanuclear Zr/Pd complexes with bridging bifunctional sulfide
acetate ligands, J. Chem. Soc. Dalton Trans.,478-480.
Wheatly N. and Kalck P.,(1999),Structure and reactivity of early- late
heterobimetallice complexes, Chem. Rev., 99,3379.
Yousif E.,Farina Y.,Kasar K.,Grasia A. and Ayid K., (2009), Complexes
of 2-thioacetic acid benzothiazole with some metal ions,
Am. J.Appl.Sci.,6(4),582-585.
Yousif E., Muaiad F. and Adil H.,(2011), Synthesis and characterization
of Fe(II), Mn(II), Co(II), Hg(II) and Cr(II) complexes of benzothiazol-
2-yl-sulfanyl)-acetic acid ligand , J.AL-Nahrain Univ., 14(1), 44.
Yousif E., Farnia Y., Grasia A., Salih N. and Salimon J., (2011),
Structure and Fangicidal activity of some diorganotin (IV) with 2-
thioacetic acid -5-phenyl-1, 3, 4-oxodiazole and benzamidophenyl
alanine, IranJ.Chem.Chem.Eng.,30,67-72.
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Published
2013-06-30
How to Cite
Buttrus, N. H. (2013). Synthesis and Characterization of Co+2,Ni+2,Cu+2 ,Zn+2 and Hg+2 Complexes With 1,1,2,2-Tetrakis (Sodium Thiolactate) Ethylene. Science Journal of University of Zakho, 1(1), 292–299. Retrieved from https://sjuoz.uoz.edu.krd/index.php/sjuoz/article/view/92
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