The Audio Frequency Conductance Study of Some Metal Succinate Salts in Aqueous Medium at Different Temperatures (Part Ii: Zinc, Nickel and Cobalt Succinates)

Authors

  • Kosrat N. Kaka University of Koya
  • Anis A. Al-Najar University of Basrah
  • Wali M. Hamad University of Koya

Keywords:

The

Abstract

The electrical conductances of aqueous solutions of zinc, nickel and cobalt succinates have been measured at four temperatures in the temperature range from 298.15K to 313.15K. The limiting molar conductances (Λo), association constants (KA) and the closest distances of approach (a) were calculated using the complete and modified forms of Fouss-Hsia (F/H) and Pitts (P). Quantitative results showed that these salts do not behave as "strong" electrolytes, and that their dissociations are far from complete. The abnormally law conductances of these electrolytes are due to the ion pair formation. The Walden product values, as well as the standard thermodynamic functions (DHo, DGo, DSo) for association reactions have been evaluated.

Author Biographies

Kosrat N. Kaka, University of Koya

Department of Chemistry, College of Science, University of Koya, Koya Town, Kurdistan – Region, Iraq.

Anis A. Al-Najar, University of Basrah

Department of Chemistry, College of Science, University of Basrah, Basrah City, Kurdistan – Region, Iraq.

Wali M. Hamad, University of Koya

Koya Technical Institute, Department of oil Refinery, Koya Town, Kurdistan – Region, Iraq.

References

Carine Livage, Chrytelle Egger and Gerard Ferey (2001), Amer. Chem. Soc., Chem. Mater, 13, 410-414.
D.J.G.Ives and H.L.Riley (1931), J.Chem.Soc., 11, 1998.
E. PITTS (1953), Proc. R. Soc. A, 217, 43.
G.Franchini, E.Ori, C.Preti, L.Tassi and G.Tosi (1987), Can.J.Chem., 65, 722.
Kosrat N. Kaka, Anis A. Alnajar and Wali M. Hamad (June 2012), Journal of Chemistry, Vol. 2013, Articles ID858374, 10 pages, in press.
Oliver Sacks "Hand book of chemistry and physics" October (2003), New York, 85th edition, 940.
R. FERNANDEZ PRINI (1969), Trans. Faraday Soc. 65, 3311.
R. M. Fuoss and F. Accasina (1959), Electrolytic conductance. 1st ed.Interscience Publishers Inc., New York.196
R. M. Fuoss and K. L. HSIA (1967), Proc. Nat. Acad. Sci. 57, 1550; 58, 1818.
References cited in A.Apelblat (2002), J.Molecular Liquids, 95, 99 – 145.
Vesna Sokol, Ivo Tominic, Renato Tomus and Marija Visic (2005), Croat.Chem.Acta., 78(1), 43-47.
W.C.Vosburgh and J.F.Beckman (1940), J.Amer.Chem.Soc., 62, 1028.
Zhao-Hui Zhou, Jin-Mei Yang and Hui-Lin Wan (2005), Crystal Growth and Design, 5(5), 1825-1830.

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Published

2013-09-30

How to Cite

Kaka, K. N., Al-Najar, A. A., & Hamad, W. M. (2013). The Audio Frequency Conductance Study of Some Metal Succinate Salts in Aqueous Medium at Different Temperatures (Part Ii: Zinc, Nickel and Cobalt Succinates). Science Journal of University of Zakho, 1(2), 780–790. Retrieved from https://sjuoz.uoz.edu.krd/index.php/sjuoz/article/view/388

Issue

Vol. 1 No. 2 (2013): September, 2013

Section

Science Journal of University of Zakho

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