Synthesis and Characterization of Co+2,Ni+2,Cu+2 ,Zn+2 and Hg+2 Complexes With 1,1,2,2-Tetrakis (Sodium Thiolactate) Ethylene

  • N. H. Buttrus University of Mosul
Keywords: sodium thiolactate, direct reaction, tetranuclear complexes

Abstract

The new ligand 1,1,2,2-tetrakis(sodium thiolactate) ethylene, has been prepared from the reaction of disodium salt of thiolactic acid and tetrachloroethylene in (4:1) molar ratio. Di and tetranuclear complexes were obtained by direct reaction of the above ligand with Co+2,Ni+2,Cu+2 , Zn+2 and Hg+2 metal ion in (1:2) and (1:4) ligand to metal molar ratio.

The prepared complexes were characterized by elemental analysis, spectral studies (FTIR.,UV/vis), magnetic measurements, conductivity measurements. Electronic spectra and magnetic moment values indicate the presence of tetrahedral geometric around the metal ions.

Author Biography

N. H. Buttrus, University of Mosul

Chemistry Department, College of Science, Mosul University, Mosul-IRAQ

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Published
2013-06-30
How to Cite
Buttrus, N. (2013). Synthesis and Characterization of Co+2,Ni+2,Cu+2 ,Zn+2 and Hg+2 Complexes With 1,1,2,2-Tetrakis (Sodium Thiolactate) Ethylene. Science Journal of University of Zakho, 1(1), 292-299. Retrieved from https://sjuoz.uoz.edu.krd/index.php/sjuoz/article/view/92
Section
Science Journal of University of Zakho