Photodegradation of 2, 4, 5, 6-Tetrachloroisophthalonitrile (Chlorothalonil) by Visible and Ultraviolet Light in the Presence of ZnO and TiO2
DOI:
https://doi.org/10.25271/sjuoz.2019.7.3.605Keywords:
Chlorothalonil, Semiconductor, Rate constant, Photo-degradation, Activation energyAbstract
photocatalytic degradation of fungicides (chlorothalonil) in suspension aqueous solution with semiconductors (tio2, zno) and without semiconductor has been investigated. the influence of different parameters such as light sources, the concentration of fungicides, type of semiconductors and temperature were studied by uv-visible spectrophotometer at 232 and 254 nm. the degradation reaction order spectra of chlorothalonil were determined which first order at 232 nm and second order at 254 nm. in addition, the rate constant, arrhenius factor and energy of activation can be estimated for both peaks. moreover, conductivity of chlorothalonil has been recorded during the photo-degradation and the rate of reaction also has been determined that dependent on product formation.
References
Atkin's, P., & Julio, D. (2006). physical chemistry, Eight Edition: (oxford: Oxford University Press).
Chiron, S., Fernandez-alba, A. & Rodriguez, A. (2000) Review paper pesticide chemical oxidation: State-of-the–art, water research, 34(2), 366-377.
Cooke, M., V., Oviedo, M., B., Pelaez, W., J. & Argüello., G., A. (2017). UV characterization and photodegradation mechanism of the fungicide chlorothalonil in the presence and absence of oxygen, Chemosphere, 187, 156-162.
Fatma, M., J., Naman, S. A., & Lazgin., A., J. (2006). photocatalytic degradation herbicides (propanil) using semicounductor (TiO¬2,ZnO) In aqueous solution and Its application in local water in dohuk. Msc. thesis (duhok: university of duhok).
Fenner, K., Canonica, S.,Wackett, L. P., & Elsner, M. (2013). Evaluating Pesticide Degradation in the Environment: Blind Spots and Emerging Opportunities, Science, 341 (6147), 752–758.
Laxma, R., P., & Ki-Hyun, K. (2015). A review of photochemical approaches for the treatment of a wide range of pesticides. Journal of Hazard Material, 285, 325-335.
Laxma. R., P, Ki-Hyun K., & Hocheol, S. (2013). Emerging green chemical technologies for the conversion of CH4 to value added products, Renewable and Sustainable Energy Reviews, 24, 578-585.
Girouda, N., b., Dorgea, S., & Trouvéa, G. (2010). Mechanism of thermal decomposition of a pesticide for safety concerns: Case of Mancozeb. Journal of Hazardous Materials. 184(1–3), 6-1.
Ormad, P., Cortes, S., Puig, A., & Ovelleiro, J., L. (1997). Degradation of organochloride compounds by O3 and O3/H2O2. Water Reserch, 31(9), 2387-2391.
Osvaldo, S., & Fabio, S., & Alfredo, N. (2007). Thermal degradation of pesticides under oxidative conditions Journal of Analytical and Applied pyrolysis, 80, 61-76.
Polyxeni, N., S., Sotirios, M., Chrysanthi, K., Panagiotis, S., & Luc, H. (2016). Chemical Pesticides and Human Health: The Urgent Need for a New Concept in Agriculture Front Public Health, 4, 148.
Sakkas, V., A., Lambropoulou, D., A., & Albanis, T., A. (2002). Study of chlorothalonil photodegradation in natural waters and in the presence of humic substances. Chemosphere, 48(9), 939-945.
Shayeghi, M., Dehghani, M., Alimohammadi, M. & Goodini, K. (2012). Using ultraviolet irradiation for removal of malathion pesticide in water. Journal of Arthropod Borne Disease, 6(1), 45–53.
Shinwar, A., Idrees, Naman, S., A., & Anees, A. (2015) Photodegradation of Trifluralin in Suspension Aqueous Solution of Acetonitrile/Water. Msc. thesis (zakho: university of zakho).
Sheren, O., I., Naman, S., A., & Lazgin, A., J. (2010). photocatalytic degradation and mineralization of paraquate, carbendazim, Acetamiprid as pesticides. Phd. desertation (zakho: university of zakho).
Toshiyuki, K. (2004). Photodegradation of Pesticides on Plant and Soil Surfaces. Review of Environmental Contamination and Toxicology, 182, 1-195.
Chiron, S., Fernandez-alba, A. & Rodriguez, A. (2000) Review paper pesticide chemical oxidation: State-of-the–art, water research, 34(2), 366-377.
Cooke, M., V., Oviedo, M., B., Pelaez, W., J. & Argüello., G., A. (2017). UV characterization and photodegradation mechanism of the fungicide chlorothalonil in the presence and absence of oxygen, Chemosphere, 187, 156-162.
Fatma, M., J., Naman, S. A., & Lazgin., A., J. (2006). photocatalytic degradation herbicides (propanil) using semicounductor (TiO¬2,ZnO) In aqueous solution and Its application in local water in dohuk. Msc. thesis (duhok: university of duhok).
Fenner, K., Canonica, S.,Wackett, L. P., & Elsner, M. (2013). Evaluating Pesticide Degradation in the Environment: Blind Spots and Emerging Opportunities, Science, 341 (6147), 752–758.
Laxma, R., P., & Ki-Hyun, K. (2015). A review of photochemical approaches for the treatment of a wide range of pesticides. Journal of Hazard Material, 285, 325-335.
Laxma. R., P, Ki-Hyun K., & Hocheol, S. (2013). Emerging green chemical technologies for the conversion of CH4 to value added products, Renewable and Sustainable Energy Reviews, 24, 578-585.
Girouda, N., b., Dorgea, S., & Trouvéa, G. (2010). Mechanism of thermal decomposition of a pesticide for safety concerns: Case of Mancozeb. Journal of Hazardous Materials. 184(1–3), 6-1.
Ormad, P., Cortes, S., Puig, A., & Ovelleiro, J., L. (1997). Degradation of organochloride compounds by O3 and O3/H2O2. Water Reserch, 31(9), 2387-2391.
Osvaldo, S., & Fabio, S., & Alfredo, N. (2007). Thermal degradation of pesticides under oxidative conditions Journal of Analytical and Applied pyrolysis, 80, 61-76.
Polyxeni, N., S., Sotirios, M., Chrysanthi, K., Panagiotis, S., & Luc, H. (2016). Chemical Pesticides and Human Health: The Urgent Need for a New Concept in Agriculture Front Public Health, 4, 148.
Sakkas, V., A., Lambropoulou, D., A., & Albanis, T., A. (2002). Study of chlorothalonil photodegradation in natural waters and in the presence of humic substances. Chemosphere, 48(9), 939-945.
Shayeghi, M., Dehghani, M., Alimohammadi, M. & Goodini, K. (2012). Using ultraviolet irradiation for removal of malathion pesticide in water. Journal of Arthropod Borne Disease, 6(1), 45–53.
Shinwar, A., Idrees, Naman, S., A., & Anees, A. (2015) Photodegradation of Trifluralin in Suspension Aqueous Solution of Acetonitrile/Water. Msc. thesis (zakho: university of zakho).
Sheren, O., I., Naman, S., A., & Lazgin, A., J. (2010). photocatalytic degradation and mineralization of paraquate, carbendazim, Acetamiprid as pesticides. Phd. desertation (zakho: university of zakho).
Toshiyuki, K. (2004). Photodegradation of Pesticides on Plant and Soil Surfaces. Review of Environmental Contamination and Toxicology, 182, 1-195.
Downloads
Published
2019-09-30
How to Cite
Salih, R. N., & Naman, S.-A. (2019). Photodegradation of 2, 4, 5, 6-Tetrachloroisophthalonitrile (Chlorothalonil) by Visible and Ultraviolet Light in the Presence of ZnO and TiO2. Science Journal of University of Zakho, 7(3), 79–88. https://doi.org/10.25271/sjuoz.2019.7.3.605
Issue
Section
Science Journal of University of Zakho
License
Authors who publish with this journal agree to the following terms:
- Authors retain copyright and grant the journal right of first publication with the work simultaneously licensed under a Creative Commons Attribution License [CC BY-NC-SA 4.0] that allows others to share the work with an acknowledgment of the work's authorship and initial publication in this journal.
- Authors are able to enter into separate, additional contractual arrangements for the non-exclusive distribution of the journal's published version of the work, with an acknowledgment of its initial publication in this journal.
- Authors are permitted and encouraged to post their work online.
