Adsorption Behavior of Copper in Some Calcareous Soils from Duhok Governorate
Keywords:
copper, adsorption, calcareous soils, thermodynamic parametersAbstract
Soil samples were taken from the surface layer of eight locations (Smail Ava, Khanki, Khirshanya, Esyan, Mahed, Suwaratoka, Bamerny and Tirwanish) Duhok governorate -Iraqi Kurdistan region, to evaluate the adsorption and thermodynamic parameters of copper (Kº, ∆Gº, ∆Hº and ∆Sº) which were determined using adsorption data and Cu2+ in equilibrium solution at two different temperature. The results demonstrated that an concentration increasing in adsorbed Cu2+with increasing added Cu2+ and temperature in all studied soils. The values of the thermodynamic equilibrium constant (Kº) and ∆Gº increased with increasing temperature from (25 to 48) °C. The values of ΔGº of both temperatures (25°C and 48°C) were negative, ranged from (-16.505 to -17.346 and -18.658 to -21.519) kJ mol-1 respectively, these negative values designate that the adsorption process is spontaneous. Enthalpy (ΔHº) and entropy (∆Sº) of studied soils were positive and varied from (2.678 to 36.716) kJ mol-1 and (66.466 to 181.417) J mol-1K-1. The positive results of (ΔHº) showed that Cu2+ adsorption is an endothermic reaction. The results also revealed that alkaline calcareous soils in Duhok adsorbed high quantities of Cu2+ and thermodynamic parameters are helpful in describing Cu2+ adsorption. The high value of Kº, ∆Gº, ∆Hº and ∆Sº for copper at 25°C and 48°C were found in soil of Smail Ava location, but low value of ∆Hº and ∆Sº for copper initiate in soil of Suwaratoka location. The type of adsorption process in Khirshanya and Suwaratoka locations can be explained by ion exchange because the mean free energy of adsorption (E) value in both locations were less than 16 kJ mol-1.
References
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Undabeytia, T., S. Nir, G. Rytwo, C. Serban, E. Morillo and C. Magueda, 2002. Modeling adsorption- desorption processes of Cu on edge and planar sites of montmorillonite. Environ. Sci. Technol., 36 (12): 2677-2683.
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Xiong, X., F. Stagnitti, G. Allinson, N. Turoczy, P. Li, M. LeBlanc, M. A. Cann, S. H. Doerr, T. S. Steenhuis, J. Y. Parlange, G. de Rooij, C. J. Ritsema and L. W. Dekker, 2005. Effects of clay amendment on adsorption and desorption of copper in water repellent soils. Australian Journal of Soil Research, 43, 397–402
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Adhikari T, Singh MV., 2003. Sorption characteristics of lead and cadmium in some soils of India. Geoderma; 114: 81-92.
Alcacio, TE., D. Hesterberg, W.Q. Chou, J.D. Martil. S. BueaUuceinii and D. E. Sayers, 2001. Molecular scale characteristics of Cu bonding in goethite - hrumate complexes. Geochem. Cosmocimiil. Acta 65:1355-1366.
Atanassova. I .D. and MI. Okazaki. 1997. Adsorption-desorption characteristics of high levels of copper in soil clay fractions. Water Air Soil Pollute. 98:213-228.
Baker. D. E., 1990. Copper. p. 151-176. In B.J. Alloway (ed.) Heavy metals in soils. Blackie and Sons Ltd., London.
Bertsch, P. and J. C. Seaman. 1999. Characterization of complex mineral assemblages: Implications for contaminant transport and environmental remediation. Proc. Nati. Acad. Sci. USA 96:3350-3357.
Biggar, J. E. and Cheung MW., 1973. A thermodynamic approach to the adsorption mechanism. Soil Science Society of America Proceeding; 37:863-868.
Bouberka, Z., Kacha S., Kameche M., Elmaleh S. and Derriche Z., 2005. Sorption study of an acid dye from an aqueous solutions using modified clays. Journal of Hazardous Materials. 119:117-124.
Dabrowski, A., 2001. Adsorption-from theory to practice, Adv. Colloid Interface Sci.93. P: 135–224.
Dali-youcef N., Oddane B. and Drriche Z., 2006. Adsorption of zinc on natural sediment of Tafna River (Journal of Soil Science Algeria). Journal of Hazardous Materials; 137:1263–1270.
Dubinin, M. M. and Radushkevich, L. V., 1947. Equation of the characteristic curve of activated charcoal.Chem. Zentr., 1, 875–890.
Dubinin, M. M., 1960. The potential theory of adsorption of gases and vapors for adsorbents with energetically non-uniform surface. Chem. Rev., 60, 235 –266.
Dudley, L. M., J. E. Mclean, T. H. Furst and J. J. Jurinak, 1991. Sorption of cadmium and copper from an acid mine waste extract by two calcareous soils: Column studies. Soil Sci., 151(2): 121-135.
Elliot H. A, Liberaty M. R. and Huang C. D., 1986. Competitive adsorption of heavy metals by soils. Journal of Environmental Quality. 15: 214-219. 8.
Frost, A. A. and Pearson, R. G., 1961. Kinetics and Mechanism. Wiley, New York, N.Y.
Goldberg, S., 2002. Competitive adsorption of arsenate and arsenite on oxides and clay minerals; Soil Sci. Soc. Am. J., 66: 413– 421.
Gunay A., E. Arslankaya and I. Tosun, 2007. Lead removal from aqueous solution by natural and pretreated clinoptilolite: adsorption equilibrium and kinetics, J. Hazard. Mater. 146 p: 362–371.
Harun, M., Kenyanya, O. and Muthengia, Jackson, 2013. Determination of Potassium Levels in Intensive Subsistence Agricultural Soils in Nyamira County, Kenya. URI: http://ir-library .ku. ac. ke /handle / .
Helfferich F. 1962. Ion Exchange. McGraw Hill, New York, USA.
Hosseinpur, A. R. and F. Dandanmozd, 2010. Sorption characteristics of copper in some calcareous soils of western Iran. Journal of American Science 6 (11).
Igwe, J. C. and A. A. Abia, 2007. Adsorption isotherm studies of Cd (II), Pb (II) and Zn (II) ions bioremediation from aqueous solution using unmodified and EDTA-modified maize cob. Ecl. Quím., São Paulo, 32(1): 33-42.
Jacobs, L., 2008. Micronutrients Needed by Crops. MWEA Bio solids Conference Bay City, Michigan. Michigan State University.
Karatanasis A. D. 1999. Subsurface migration of copper and zinc mediated by soil colloids. Soil Sc. Soc. of Am. J., 63:830-838.
Lindsay, W. L. and Norvell W. A., 1978. Development of a DTPA soil test for zinc, iron, manganese, and copper. Soil Sci. Soc. Am. J., 42:421–428.
Liu, G., N. Jiang, L. Zhang and Z. Liu, 1996. Methods of soil physicochemical analysis and profile description. Chinese Standard Press, Beijing.
Mahler, Robert L., 2004. Nutrients Plants Require for Growth. University of Idaho Extension CIS 682. Idaho Agricultural Experiment Station.
McBride, M. B., 1994. Environmental chemistry of soils. Oxford Univ. Press, Oxford.
Mocqluot, B., J. Vangronsveld, H. Clijsters and M. Mench, 1996. Copper toxicity in young maize (Zen umys L.) plants: Effects on growth, mineral and chlorophyll contents, and enzyme activities. Plant Soil. 182:287-300.
Nelson, D. W. and Sommers L. E., 1996. Total carbon, organic carbon, and organic matter. In: Sparks DL, ed. Methods of soil analysis, ASA Madison, Wisconsin, USA; 961-1010.
Rhoades, J. D., 1996. Salinity: Electrical conductivity and total dissolved solids. In: Sparks DL, ed. Methods of soil analysis. SSSA. Madison, Wisconsin, USA; 417-435.
Selim, H. M.1992. Modeling the transport and retention of inorganics in soils. Adv. In Agron. 47, 331.
Sparks, D. L. 1995. Environmental Soil Chemistry. Academic Press, San Diego, CA.
Summer, ME. and Miller W. P., 1996. Cation exchange capacity and exchange coefficient. In: Sparks DL, ed. Methods of soil analysis, SSSA Madison, Wisconsin,;1201-1231.
Undabeytia, T., S. Nir, G. Rytwo, C. Serban, E. Morillo and C. Magueda, 2002. Modeling adsorption- desorption processes of Cu on edge and planar sites of montmorillonite. Environ. Sci. Technol., 36 (12): 2677-2683.
Unlu N, Ersoz M., 2006. Adsorption characteristics of heavy metal ions onto a low cost biopolymeric sorbent from aqueous solutions. Journal of Hazardous Materials; 136: 272–280.
Xiong, X., F. Stagnitti, G. Allinson, N. Turoczy, P. Li, M. LeBlanc, M. A. Cann, S. H. Doerr, T. S. Steenhuis, J. Y. Parlange, G. de Rooij, C. J. Ritsema and L. W. Dekker, 2005. Effects of clay amendment on adsorption and desorption of copper in water repellent soils. Australian Journal of Soil Research, 43, 397–402
Yavuz, O., Altunkaynak Y. and Guzel F., 2003. Removal of copper, nickel, cobalt and manganese from aqueous solution by kaolinite. Water Research. 37:948–952.
Yu, S., Z. L. He, C. Y. I. Huang, G. C. Chen, and D. V. Calvert, 2002. Adsorption-Desorption Behavior of Copper at Contaminated Levels in Red Soils from China. J. Environ. Qual. 31:1129-1136.
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2016-12-30
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Mehmedany, L. A. M., Hashim, F. A., & Barwari, V. I. H. (2016). Adsorption Behavior of Copper in Some Calcareous Soils from Duhok Governorate. Science Journal of University of Zakho, 4(2), 200–207. Retrieved from https://sjuoz.uoz.edu.krd/index.php/sjuoz/article/view/351
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